Can you use volume to measure out a mole of a gas? Why or why not?

Chemistry · College · Thu Feb 04 2021

Answered on

Yes, you can use volume to measure out a mole of a gas under specific conditions. At standard temperature and pressure (STP), which is defined as 0 degrees Celsius (273.15 K) and 1 atmosphere (atm) of pressure, one mole of an ideal gas occupies 22.4 liters. This is known as the molar volume of a gas at STP.

To measure out a mole of a gas using volume, you need to make sure that the gas is behaving ideally, which means that its molecules are not interacting with each other in a significant way, and it must be under the conditions of STP. If the temperature and pressure deviate from STP, the volume occupied by a mole of the gas will also change according to the Ideal Gas Law, which is PV = nRT (where P is pressure, V is volume, n is the number of moles, R is the gas constant, and T is the temperature in Kelvin).

For example, if you have the gas at STP and you measure out 22.4 liters of that gas, you will have one mole of the ideal gas in the container.

Extra: The Ideal Gas Law provides a way to predict and calculate the behavior of an ideal gas. While no real gas is perfectly ideal, many gases behave ideally at a range of conditions that are not extreme, making the Ideal Gas Law useful for practical calculations.

The law states that the pressure (P) of a given quantity of gas is directly proportional to its absolute temperature (T), and inversely proportional to its volume (V), assuming the amount of gas (in moles, n) and the gas constant (R) are constant. Therefore, the law can be rearranged to solve for any one of these variables if the other three are known.

The value of R, the gas constant, depends on the units used for the other terms and must be consistent with them. Common values for R include 0.0821 L·atm/(K·mol) if pressure is measured in atmospheres and volume in liters, and 8.314 J/(K·mol) if pressure is measured in pascals and volume in cubic meters.

In a classroom setting, experiments are often conducted at or corrected to STP so that calculations can be simplified, and volumes can be directly related to moles using the 22.4 L/mol equivalence for many gases. Practical applications include determining the amount of reactant or product gas in chemical reactions or the mass of a gas if its molar mass is known.