Using this formula to find K, what does E0 represent? A) cell potential B) electrons transferred C) equilibrium constant D) free energy change E) Gibbs free energy change

Chemistry · High School · Sun Jan 24 2021

Answered on

A) cell potential

  • In the context of the formula typically used to find the equilibrium constant (K) in electrochemistry, which relates the standard cell potential (\(E^0\)) to the Gibbs free energy change and the equilibrium constant, \(E^0\) represents the standard cell potential. The formula often referenced is the Nernst equation, which at standard conditions (when all reactants and products are at 1 M concentration and 25°C), can be simplified to relate \(E^0\) to the equilibrium constant (K).

The relationship is given by the following equation:

  • \[ E^0 = \frac{RT}{nF} \ln(K) \]
  • Or more commonly in logarithmic form as:
  • \[ E^0 = \frac{0.0592V}{n} \log(K) \]
  • Here, \(R\) is the ideal gas constant, \(T\) is the temperature in Kelvin, \(n\) is the number of moles of electrons transferred, \(F\) is Faraday's constant, and \(K\) is the equilibrium constant.

Related Questions