Using this formula to find K, what does E0 represent? A) cell potential B) electrons transferred C) equilibrium constant D) free energy change E) Gibbs free energy change
Chemistry · High School · Sun Jan 24 2021
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A) cell potential
- In the context of the formula typically used to find the equilibrium constant (K) in electrochemistry, which relates the standard cell potential (\(E^0\)) to the Gibbs free energy change and the equilibrium constant, \(E^0\) represents the standard cell potential. The formula often referenced is the Nernst equation, which at standard conditions (when all reactants and products are at 1 M concentration and 25°C), can be simplified to relate \(E^0\) to the equilibrium constant (K).
The relationship is given by the following equation:
- \[ E^0 = \frac{RT}{nF} \ln(K) \]
- Or more commonly in logarithmic form as:
- \[ E^0 = \frac{0.0592V}{n} \log(K) \]
- Here, \(R\) is the ideal gas constant, \(T\) is the temperature in Kelvin, \(n\) is the number of moles of electrons transferred, \(F\) is Faraday's constant, and \(K\) is the equilibrium constant.